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Ammonium iodide-mediated electrosynthesis of unsymmetrical thiosulfonates from arenesulfonohydrazides and thiols

Terent'ev A. O., Mulina O. M., Ilovaisky A. I., Kokorekin V. A., Nikishin G. I.
Mendeleev Communications
Vol.29, Issue1, P. 80-82
Опубликовано: 2019
Тип ресурса: Статья

DOI:10.1016/j.mencom.2019.01.027

Аннотация:
Unsymmetrical thiosulfonates were synthesized from thiols and arenesulfonohydrazides by their electrolysis in undivided cell equipped with graphite anode and stainless steel cathode under high current density applying NH 4 I both as a redox catalyst and a supporting electrolyte. In the course of the process, oxidative formation of S–S bond occurs with the loss of hydrazine moiety. © 2019
Язык текста: Английский
ISSN: 1364-551X
Terent'ev A. O.
Mulina O. M.
Ilovaisky A. I.
Kokorekin V. A. Vladimir Alekseevich 1987-
Nikishin G. I.
Терент'ев А. О.
Мулина О. М.
Иловаискy А. И.
Кокорекин В. А. Владимир Алексеевич 1987-
Никишин Г. И.
Ammonium iodide-mediated electrosynthesis of unsymmetrical thiosulfonates from arenesulfonohydrazides and thiols
Текст визуальный непосредственный
Mendeleev Communications
Elsevier Science Publisher B.V.
Vol.29, Issue1 P. 80-82
2019
Статья
Unsymmetrical thiosulfonates were synthesized from thiols and arenesulfonohydrazides by their electrolysis in undivided cell equipped with graphite anode and stainless steel cathode under high current density applying NH 4 I both as a redox catalyst and a supporting electrolyte. In the course of the process, oxidative formation of S–S bond occurs with the loss of hydrazine moiety. © 2019