Alkoxy aluminum chlorides in the cationic polymerization of isobutylene: A co-initiator, carbocation stabilizer and chain-transfer agent
Shiman D. I., Vasilenko I. V., Kostuk S. V.
Polymer Chemistry
Vol.10, Issue44, P. 5998-6002
Опубликовано: 2019
Тип ресурса: Статья
Аннотация:
Alkoxy aluminum chlorides are efficient catalysts for the preparation of well-defined exo-olefin terminated PIBs of low (Mn ∼ 1000 g mol-1) to medium (Mn up to 50000 g mol-1) molecular weight under mild experimental conditions (n-hexane as a solvent, [IB] = 5.8 M, temperature from -20 °C to 20 °C). © 2019 The Royal Society of Chemistry.
Ключевые слова:
Aluminum compounds; Cationic polymerization; Chlorine compounds; Hexane; Organic solvents; Carbocations; Chain transfer agents; Co-initiators; Efficient catalysts; Experimental conditions; N hexane; Aluminum chloride
Язык текста: Английский
ISSN: 1759-9962
Shiman D. I.
Vasilenko I. V.
Kostuk S. V. Sergej Viktorovich 1977-
Шиман Д. И.
Василенко И. В.
Костюк С. В. Сергей Викторович 1977-
Alkoxy aluminum chlorides in the cationic polymerization of isobutylene: A co-initiator, carbocation stabilizer and chain-transfer agent
Текст визуальный непосредственный
Polymer Chemistry
Vol.10, Issue44 P. 5998-6002
2019
Статья
Aluminum compounds Cationic polymerization Chlorine compounds Hexane Organic solvents Carbocations Chain transfer agents Co-initiators Efficient catalysts Experimental conditions N hexane Aluminum chloride
Alkoxy aluminum chlorides are efficient catalysts for the preparation of well-defined exo-olefin terminated PIBs of low (Mn ∼ 1000 g mol-1) to medium (Mn up to 50000 g mol-1) molecular weight under mild experimental conditions (n-hexane as a solvent, [IB] = 5.8 M, temperature from -20 °C to 20 °C). © 2019 The Royal Society of Chemistry.