Bond cleavage in hydroxyl derivatives initiated by electron transfer: electroreduction of 9H,9'H-bifluorene-9,9’-diol
Mendkovich A. S., Syroeshkin M. A., Mitina K. R., Mikhailov M. N., Gultyai V. P., Pechennikov V. M.
Mendeleev Communications
Vol.27, Issue6, P. 580-582
Опубликовано: 2017
Тип ресурса: Статья
DOI:10.1016/j.mencom.2017.11.014
Аннотация:
Cyclic voltammetry, digital simulation and quantum chemical methods were applied to study the electroreduction mechanism of vicinal hydroxyl derivatives using 9H,9'H-bifluorene- 9,9’-diol as an example. Unlike the case of fluoren-9-ol, dissociation of the C9–C9’ bond rather than the C9–OH one occurs in radical anion of the substrate, similarly to that in radical cations formed upon oxidation of vicinal hydroxyl derivatives. © 2017
Язык текста: Английский
ISSN: 1364-551X
Mendkovich A. S.
Syroeshkin M. A.
Mitina K. R.
Mikhailov M. N.
Gultyai V. P.
Pechennikov V. M. Valerij Mikhaylovich 1943-
Мендкович А. С.
Сyроешкин М. А.
Митина К. Р.
Михаилов М. Н.
Гултяи В. П.
Печенников В. М. Валерий Михайлович 1943-
Bond cleavage in hydroxyl derivatives initiated by electron transfer: electroreduction of 9H,9'H-bifluorene-9,9’-diol
Текст визуальный непосредственный
Mendeleev Communications
Elsevier Science Publisher B.V.
Vol.27, Issue6 P. 580-582
2017
Статья
Cyclic voltammetry, digital simulation and quantum chemical methods were applied to study the electroreduction mechanism of vicinal hydroxyl derivatives using 9H,9'H-bifluorene- 9,9’-diol as an example. Unlike the case of fluoren-9-ol, dissociation of the C9–C9’ bond rather than the C9–OH one occurs in radical anion of the substrate, similarly to that in radical cations formed upon oxidation of vicinal hydroxyl derivatives. © 2017