Solvent-free Buchwald–Hartwig amination with low palladium loadings
Chesnokov G. A., Gribanov P. S., Topchiy M. A., Minaeva L. I., Asachenko A. F., Nechaev M. S., Bermesheva E. V., Bermeshev M. V.
Mendeleev Communications
Vol.27, Issue6, P. 618-620
Опубликовано: 2017
Тип ресурса: Статья
DOI:10.1016/j.mencom.2017.11.027
Аннотация:
A highly efficient ‘green’ solvent-free monoarylation of primary anilines with aryl bromides mediated by the expanded-ring N-heterocyclic carbene palladium complex (THP-Dipp)Pd(cinn)Cl [THP-Dipp is 1,3-bis(2,6-diisopropylphenyl)-3,4,5,6-tetrahydropyrimidin-2-ylidene; cinn is cinnamyl] can be performed at low catalyst loadings (0.1 mol[%]) to provide excellent yields and remarkable selectivities for various substrates. © 2017
Язык текста: Английский
ISSN: 1364-551X
Chesnokov G. A.
Gribanov P. S.
Topchiy M. A.
Minaeva L. I.
Asachenko A. F.
Nechaev M. S.
Bermesheva E. V. Evgeniya Vladimirovna 1983-
Bermeshev M. V.
Чесноков Г. А.
Грибанов П. С.
Топчиy М. А.
Минаева Л. И.
Асаченко А. Ф.
Нечаев М. С.
Бермешева Е. В. Евгения Владимировна 1983-
Бермешев М. В.
Solvent-free Buchwald–Hartwig amination with low palladium loadings
Текст визуальный непосредственный
Mendeleev Communications
Elsevier Science Publisher B.V.
Vol.27, Issue6 P. 618-620
2017
Статья
A highly efficient ‘green’ solvent-free monoarylation of primary anilines with aryl bromides mediated by the expanded-ring N-heterocyclic carbene palladium complex (THP-Dipp)Pd(cinn)Cl [THP-Dipp is 1,3-bis(2,6-diisopropylphenyl)-3,4,5,6-tetrahydropyrimidin-2-ylidene; cinn is cinnamyl] can be performed at low catalyst loadings (0.1 mol[%]) to provide excellent yields and remarkable selectivities for various substrates. © 2017