Reductive silylation of gem-difluorinated phosphonium salts
Tsymbal A. V., Levin V. V., Struchkova M. I., Kokorekin V. A., Korlyukov A. A., Dilman A. D.
Journal of Fluorine Chemistry
Vol.205, P. 58-61
Опубликовано: 2018
Тип ресурса: Статья
DOI:10.1016/j.jfluchem.2017.11.009
Аннотация:
gem-Difluorinated phosphonium salts, generated from aldehydes and difluorinated phosphobetaine reagent, were converted into corresponding silicon reagents. The reductive silylation of carbon-phosphorus bond is carried out using a combination of magnesium and chlorotrimethylsilane in dimethylformamide. For a model difluoroined phosphonium salt, X-ray structure and reduction potential are provided. © 2017 Elsevier B.V.
Ключевые слова:
Difluorinated compounds; Phosphonium salts; Reductive silylation; Silicon reagents
Язык текста: Английский
ISSN: 1873-3328
Tsymbal A. V.
Levin V. V.
Struchkova M. I.
Kokorekin V. A. Vladimir Alekseevich 1987-
Korlyukov A. A.
Dilman A. D.
Цyмбал А. В.
Левин В. В.
Стручкова М. И.
Кокорекин В. А. Владимир Алексеевич 1987-
Корлюков А. А.
Дилман А. Д.
Reductive silylation of gem-difluorinated phosphonium salts
Текст визуальный непосредственный
Journal of Fluorine Chemistry
Elsevier Science Publisher B.V.
Vol.205 P. 58-61
2018
Статья
Difluorinated compounds Phosphonium salts Reductive silylation Silicon reagents
gem-Difluorinated phosphonium salts, generated from aldehydes and difluorinated phosphobetaine reagent, were converted into corresponding silicon reagents. The reductive silylation of carbon-phosphorus bond is carried out using a combination of magnesium and chlorotrimethylsilane in dimethylformamide. For a model difluoroined phosphonium salt, X-ray structure and reduction potential are provided. © 2017 Elsevier B.V.