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Specific Features of the Molecular Structure of A New 3-(Benzo[d]Oxazole-2-Yl)- 1-(2-(1,3,3-Trimethylindoline-2-Ylidene)...

Tkachev V. V., Uteny'shev A. N., Chernyshov A. I., Kovalchukova O. V.
Journal of Structural Chemistry
Vol.59, Issue2, P. 425-428
Опубликовано: 2018
Тип ресурса: Статья

DOI:10.1134/S0022476618020245

Аннотация:
X-ray diffraction is used to determine the structure of a new 3-(benzo[d]oxazole-2-yl)-1-(2-(1,3,3- trimethylindoline-2-ylidene)ethylidene)naphthalene-2(1H)-one zinc chloride complex 1. It is demonstrated that the ligand molecule in complex 1 has a trans–trans–cis conformation in which the indoline nitrogen atom is oriented in the same direction as the chelate ring, which could promote an additional coordination with the complexing atom. © 2018, Pleiades Publishing, Ltd.
Ключевые слова:
3-(benzo[d]oxazole-2-yl)-1-(2-(1,3,3-trimethylindoline-2-ylidene)ethylidene)naphthalene-2(1H)-one zinc chloride; spiropyrans; X-ray diffraction study
Язык текста: Английский
ISSN: 1573-8779
Tkachev V. V.
Uteny'shev A. N. Andrej Nikolaevich 1966-
Chernyshov A. I.
Kovalchukova O. V.
Ткачев В. В.
Утенышев А. Н. Андрей Николаевич 1966-
Чернyшов А. И.
Ковалчукова О. В.
Specific Features of the Molecular Structure of A New 3-(Benzo[d]Oxazole-2-Yl)- 1-(2-(1,3,3-Trimethylindoline-2-Ylidene) Ethylidene)Naphthalene-2(1H)-One Zinc Chloride Complex
Specific Features of the Molecular Structure of A New 3-(Benzo[d]Oxazole-2-Yl)- 1-(2-(1,3,3-Trimethylindoline-2-Ylidene)...
Текст визуальный непосредственный
Journal of Structural Chemistry
Pleiades Publishing, Ltd.
Vol.59, Issue2 P. 425-428
2018
Статья
3-(benzo[d]oxazole-2-yl)-1-(2-(1,3,3-trimethylindoline-2-ylidene)ethylidene)naphthalene-2(1H)-one zinc chloride spiropyrans X-ray diffraction study
X-ray diffraction is used to determine the structure of a new 3-(benzo[d]oxazole-2-yl)-1-(2-(1,3,3- trimethylindoline-2-ylidene)ethylidene)naphthalene-2(1H)-one zinc chloride complex 1. It is demonstrated that the ligand molecule in complex 1 has a trans–trans–cis conformation in which the indoline nitrogen atom is oriented in the same direction as the chelate ring, which could promote an additional coordination with the complexing atom. © 2018, Pleiades Publishing, Ltd.