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Electrosynthesis of azopyrazoles via the oxidation of N-alkylaminopyrazoles on a NiO(OH) anode in aqueous alkali – A green method for N-N homocoupling

Lyalin B. V., Sigacheva V. L., Kokorekin V. A., Petrosyan V. A.
Tetrahedron Letters
Vol.59, Issue28, P. 2741-2744
Опубликовано: 2018
Тип ресурса: Статья

DOI:10.1016/j.tetlet.2018.05.089

Аннотация:
A nickel oxyhydroxide [NiO(OH)] anode was exploited to develop a new synthetic route for the electrocatalytic N-N homocoupling of N-alkylaminopyrazoles in an alkaline aqueous medium. The advantages of this green electrochemical methodology include low cost, atom economy and high yields. © 2018 Elsevier Ltd
Ключевые слова:
Azopyrazoles; Electrocatalytic (mediated) oxidation; N-Alkylaminopyrazoles; N-N coupling; NiO(OH) anode
alkali; azopyrazole derivative; n alkylaminopyrazole derivative; nickel; nickel hydroxide; pyrazole derivative; unclassified drug; Article; catalysis; chemical reaction; chemical structure; electrochemical analysis; electrolysis; electrosynthesis; oxidation; physical chemistry; physical parameters; synthesis; X ray diffraction
Язык текста: Английский
ISSN: 0040-4039
Lyalin B. V.
Sigacheva V. L.
Kokorekin V. A. Vladimir Alekseevich 1987-
Petrosyan V. A.
Лялин Б. В.
Сигачева В. Л.
Кокорекин В. А. Владимир Алексеевич 1987-
Петросян В. А.
Electrosynthesis of azopyrazoles via the oxidation of N-alkylaminopyrazoles on a NiO(OH) anode in aqueous alkali – A green method for N-N homocoupling
Текст визуальный непосредственный
Tetrahedron Letters
Elsevier Science Publisher B.V.
Vol.59, Issue28 P. 2741-2744
2018
Статья
Azopyrazoles Electrocatalytic (mediated) oxidation N-Alkylaminopyrazoles N-N coupling NiO(OH) anode
alkali azopyrazole derivative n alkylaminopyrazole derivative nickel nickel hydroxide pyrazole derivative unclassified drug Article catalysis chemical reaction chemical structure electrochemical analysis electrolysis electrosynthesis oxidation physical chemistry physical parameters synthesis X ray diffraction
A nickel oxyhydroxide [NiO(OH)] anode was exploited to develop a new synthetic route for the electrocatalytic N-N homocoupling of N-alkylaminopyrazoles in an alkaline aqueous medium. The advantages of this green electrochemical methodology include low cost, atom economy and high yields. © 2018 Elsevier Ltd