Refinement of the Molecular Structure of Ammonium Pentachloroaquaferrate (NH4)2[FeCl5(H2O)]
Koval’chukova O. V., Strashnova S. B., Uteny'shev A. N., Strashnov P. V.
Russian Journal of Coordination Chemistry
Vol.45, Issue7, P. 512-516
Опубликовано: 2019
Тип ресурса: Статья
DOI:10.1134/S1070328419060022
Аннотация:
Abstract: The crystal structure of ammonium pentachloroaquaferrate (NH4)2[FeCl5(H2O)] is refined (CIF file CCDC no. 1831198). Compounds (А)х[FeCl5(H2O)], where A is an organic or inorganic anion (х = 1, 2), crystallize in the orthorhombic crystal system. The geometry and structural parameters of the [FeCl5(H2O)]2– anion are nearly independent of the counterion nature. © 2019, Pleiades Publishing, Ltd.
Ключевые слова:
aquaferrate complexes; iron complexes; X-ray diffraction analysis
Chlorine compounds; Crystal structure; Ions; X ray diffraction analysis; X ray powder diffraction; aquaferrate complexes; Counterions; Inorganic anions; Iron complex; Orthorhombic crystal system; Structural parameter; Iron compounds
Язык текста: Английский
ISSN: 1608-3318
Koval’chukova O. V.
Strashnova S. B.
Uteny'shev A. N. Andrej Nikolaevich 1966-
Strashnov P. V.
Ковал’чукова О. В.
Страшнова С. Б.
Утенышев А. Н. Андрей Николаевич 1966-
Страшнов П. В.
Refinement of the Molecular Structure of Ammonium Pentachloroaquaferrate (NH4)2[FeCl5(H2O)]
Текст визуальный непосредственный
Russian Journal of Coordination Chemistry
Pleiades Publishing, Ltd.
Vol.45, Issue7 P. 512-516
2019
Статья
aquaferrate complexes iron complexes X-ray diffraction analysis
Chlorine compounds Crystal structure Ions X ray diffraction analysis X ray powder diffraction aquaferrate complexes Counterions Inorganic anions Iron complex Orthorhombic crystal system Structural parameter Iron compounds
Abstract: The crystal structure of ammonium pentachloroaquaferrate (NH4)2[FeCl5(H2O)] is refined (CIF file CCDC no. 1831198). Compounds (А)х[FeCl5(H2O)], where A is an organic or inorganic anion (х = 1, 2), crystallize in the orthorhombic crystal system. The geometry and structural parameters of the [FeCl5(H2O)]2– anion are nearly independent of the counterion nature. © 2019, Pleiades Publishing, Ltd.